In order to produce chars having different thermal histories, back-coated samples of known weight were then placed in a furnace at 300, 400, and 500 and 600 °C for 5 minutes in an air atmosphere. The best results have been achieved by using 6,60-(ethane-1,2-diylbis-(azanediyl)-bis-(6H-dibenzo [c,e][1,2])-oxaphosphine-6-oxide). Main sources of release into the environment are identified as leakage or spills of hydraulic fluid, leaching from plastics, and manufacturing processes. When more than one numerical result is available per endpoint the count is displayed between square brackets. ‹ › What it is and what causes it Plasticizer additives are distributed throughout cellulose film bases. This section summarises physical and chemical property values from all registered dossiers in ECHA’s databases for the substance. Spiro(5,5)phosphonia-undecane chloride (12) was produced in low yield by the reaction of dimethylurea with the little exploited, readily available, tetrakis(hydroxymethyl)-phosphonium salts 〈81PS(10)147〉. Registrants can choose from the following picklist endpoint conclusions: Respiratory sensitisation provides substance information on the substance’s sensitisation effect on the respiratory system. Manufacturers and importers can provide the following information in the registration dossier: Hazard for Air provides information on the substance’s hazard assessment conclusion related to air. LC50 for marine water invertebrates provides substance information on the substance’s lethal concentration for 50% of the marine water invertebrates in the test, displayed in milligram per litre. MPP, or methyl phenyl phosphate, is a mixture of organophosphate flame retardants that do not contain halogens (e.g. All the source data on which the summaries on this page are based, is provided by industry and stored in the ECHA databases. SMILES notations are comprised of atoms (designated by elemental symbols), bonds, parentheses (used to show branching), and numbers (used for cyclic structures). Data is generally displayed in milligrams per kilogram in the case of soil (dry/wet weight) or gram per hectare. Different classifications can also be due to technical errors made during the notification process. It was revealed that TPP shows only a gas phase action (flame inhibition), whereas RDP shows some and BDP a crucial condensed-phase action (enhancing char formation) in addition to the gas-phase action. 1.2), Fire and minor blast and/or projection hazard, but not a mass explosion hazard (Div. This substance is used for the manufacture of: plastic products, textile, leather or fur, rubber products, electrical, electronic and optical equipment and machinery and vehicles. MDL number MFCD00003031. The data presented in these sections has been cleaned to remove names of one character or less, or names which consist solely of punctuation or numerical characters. In contrast, TPP is readily The dark blue bar illustrates the percentage of matching substance classifications provided by manufacturers and importers in a REACH registration dossier. Note: Registrants can also select ‘other’ as the unit of measure. Phthalate and triphenyl phosphate are two common plasticizers used in the manufacture of acetate film bases. RST is the consecutive number of the substance in the series ABC. In commercial PC/ABS blends where the ABS content normally does not exceed 25% it is possible to achieve a UL 94 V-0 rating with these products at 8–15 wt% loading in combination with a coadditive. These molecules have been found appropriate for PUFs in automotive applications, where fogging is critical. Sed elementum odio augue, eget iaculis lorem faucibus vel. It dissolves in non-polar organic solvents such as benzene and diethyl ether It does not represent a new labelling, classification or hazard statement. The limit of quantification for the tricresyl phosphates and triphenyl phosphate is 0.002 mg/m 3 at a sample volume of 240 L, a sample solution of 2.5 mL and an injection volume of 1 µL. Preparation. pH provides substance information on the substance’s acidity level measured in pH at a temperature measured in °C and a concentration measured in (milli)grams per litre. The physical state and form of a substance can play a significant impact when the hazards of a substance are assessed. If so, the data provided is not processed for the Brief Profile. Resorcinol bis(di-2,6-xylenyl phosphate) (RXP) is exclusively made in Japan and has a higher hydrolytic stability than RDP and BDP due to the steric hindrance by the 2,6-xylyl groups. Registrant can provide information on eye exposure by selecting one of the following hazard assessment conclusions: Data for general population – eye exposure provides information on the substance’s hazard assessment conclusions regarding eye exposure (for the general population). If more than one IUPAC name is available from REACH registered dossiers, all IUPAC names are displayed in ‘Other names’ section of the Brief Profile. Release to the environment of this substance can occur from industrial use: formulation in materials and formulation of mixtures. All phosphate esters decompose to acid species especially after exposure to high heat and humidity. It can be handled by standard plastics processing equipment, equipped with solids feeding conventional systems. Fusce eget lorem sed purus tempus blandit. They give superior performance in fogging tests. Additionally, the classification provided by companies to ECHA in CLP notifications identifies that this substance is very toxic to aquatic life with long lasting effects. The present study was an attempt to evaluate the impact of biofield treatment on physicochemical and spectroscopic properties of TPP. The Agency thus cannot guarantee the correctness of the information displayed. It is commonly used as a fire-retarding agent and plasticizer for nitrocellulose and cellulose acetate. This colourless solid is the ester (triester) of phosphoric acid and phenol. Annex V – indicates if the substance is prohibited from export. Applicant’s summary and conclusion – Interpretation of results. Displayed are the RANGES of min – max of the PRIORITISED value(s) within the five highest priority groupings of provided data. . We have shown previously that the structurally similar ligand, tributyltin, does not induce brite adipocyte gene expression. Please see Registrants/Suppliers details. If only waived data is available for the substance, following justifications for data-waiving can be displayed in the Brief Profile: Some endpoints are not included in the Brief Profile due to the use of free text and/or complex field(s) in the reporting of information, which cannot be easily summarised by an automatic algorithm. Bioaccumulation factor (terrestrial species) provides substance information on the substance’s terrestrial bioaccumulative properties not taking account the dimensions. PNEC sediment, data displayed in milligram per kilo sediment (dry weight). ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. Triphenyl phosphate. The purpose of the information provided under this section is to highlight in a readable format the substance hazardousness. The quality and correctness of the information remains the responsibility of the data submitter. 5mg/L at 20°C). Long-term EC10 or LC10 or NOEC for mammals provides substance information on the substance’s effect concentration or lethal concentration (long term) for 10% of the mammals in the test, or the no observed effect concentration for mammals. The date of the last update corresponds to the publication date of the Brief Profile and not necessarily to the date in which the update occurred in the source data (registered dossiers, the C&L Inventory or a regulatory process). More information about the EC Inventory can be found here. The invention relates to a composition of mixed alkylated triphenyl phosphate esters comprising no less than 65% to about 100%, by weight, monoalkylphenyl diphenyl phosphate, up to about 30%, by weight, dialkylphenyl phenyl phosphate, up to about 3%, by weight, trialkylphenyl phosphate, and up to about 5%, by weight, triphenyl phosphate. These experiments were not intended to simulate actual combustion conditions but were designed to create chars having residual phosphorus contents that would be dependent on the volatility of the phosphorus-containing moieties present and Table 11.7 summarizes the results of char phosphorus content analyses expressed as ΔP%, the respective phosphorus loss from each char, where ΔP equals the theoretical phosphorus content assuming 100% retention in the char minus the experimental value.21,22, Table 11.7. On the other hand, bis spirophosphazene (27) was made by the reaction of substituted phosphabenzenes with phenylazide 〈93TL3107〉. Different phosphate esters have different hydrolytic stabilities. The EC name and number are the official identifiers for substances within the European Union and can be found in the EC Inventory. It is melt blendable with polypropylene and does not require antimony trioxide as synergist, so that it can be used for fiber spinning. Data is generally standardised and displayed in milligram per litre or molar per litre. EC Inventory, Substance Evaluation - CoRAP, REACH pre-registration, Other, EC Inventory, C&L Inventory, Substance Evaluation - CoRAP, Registration dossier, REACH pre-registration, Other. As example 50 using potassium fluoride (0.5 g) and heating at 100° C. at 2 h under nitrogen to give a mixture comprising, triphenylphosphate (14 wt %), diphenyl 4-t-butyl phenylphosphate (28%), phenyl di(4-t-butyl phenyl) phosphate (40%) and tri (4-t-butyl phenyl) phosphate (18%). For this endpoint registrants do not provide summary data. Displayed are the RANGES of min – max of the PRIORITISED value(s) within the five highest priority groupings of provided data. PubChem Substance ID 24868016 This section summarises the values related to biodegradation in soil from all registered dossiers for the substance. Phototransformation in soil provides substance information on the substance’s phototransformation in soil in seconds/minutes/hours/days/weeks/months/years. ). The list of acronyms and abbreviations related to TPP - Triphenyl phosphate Long-term EC10 or LC10 or NOEC for birds provides substance information on the substance’s effect concentration or lethal concentration (long term) for 10% of the birds in the test, or the no observed effect concentration for birds. Halogen-free phosphate-based FRs are applied in PC, PC/ABS, and PPO/HIPS blends, which are extensively used for housings of business computers (mostly laptops) and other business devices. When submitted by the lead of a joint submission, the classifications may also reveal agreement between companies. This section summarises the values related to toxicity to soil macroorganisms (except arthropods) from all registered dossiers for the substance. The control sample was remained as untreated; and treatment sample was handed over in sealed pack to Mr. Trivedi for biofield treatment under laboratory conditions. Triphenyl phosphate (TPHP) is a chemical used in plastics to improve flexibility and as a flame retardant. Uses. Carlson and Ehrich (2001) tested the ability of a number of OPs including paraoxon, parathion, diisopropyl fluorophosphate (DFP), phenyl saligenin phosphate (PSP), triorthotolyl phosphate (TO TP), and triphenyl phosphite at 0.1–1 mM to disrupt the filamentous actin (F-actin) network in mitotic human using a fluorescently labeled phalloidin probe. EC50/LC50 for marine sediment provides substance information on the substance’s effect concentration or lethal concentration for 50% of the model organisms feeding off the marine sediment, generally displayed in milligrams per kilogram sediment (dry weight). This section displays the values related to irritation and corrosion from all registered dossiers for the substance. Hazard to aquatic organisms provides information on the substance’s hazard assessment conclusion regarding aquatic organisms. Dissipation Half-life of parent compound provides substance information on the substance’s dissipation half-life for the parent compound per second/minute/hour/day/week/month/year. The information has not been reviewed or verified by ECHA or any other authority. binding agent in paints and coatings or adhesives). The availability of additional data beyond the five results displayed is indicated by (…). Inhalation exposure provides information on the substance’s hazard assessment conclusions regarding inhalation exposure. EC10 / LC10 or NOEC for freshwater fish provides substance information on the substance’s effect concentration/lethal concentration for 10% of the tested freshwater fish or the no observed effect concentration. While the consumption of monoarylphosphates over the next 5 years will track the global gross domestic product, consumption of bisarylphosphates will grow at 5% per year as a result of the replacement of halogen FRs in engineering resins (PPO/HIPS, PC/ABS blend) used for the production of housings for computer monitors, TV sets, and mobile phones [4]. EC10 / LC10 or NOEC for marine water plants provides substance information on the substance’s effect concentration/lethal concentration for 10% of the tested marine water plants or the no observed effect concentration for marine water plants. The goal of CLP is to make sure that hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through a system of classifying and labelling of chemicals. Data from all dossiers registered for the same substance is used in the summarisation and aggregation process, as it is presumed that all data submitted by the registrants is relevant for the substance being registered. Also, if the registrant selects ‘ppb’; ‘vol%’ and ‘other’ as a unit of measure for the concentration value, the data provided will not be processed for the Brief Profile. A proprietary new aromatic bisphosphate, a solid powder melting at 105–108 °C, is currently introduced under the trade name Fyrolflex Sol-DP [6]. This section displays the values related to endocrine disrupter mammalian screening from all registered dossiers for the substance. Values provided in ppb and Vol% are provided separately. It is interesting to note that while the agglomerating effect of TPP at 100 parts presence resulted in a high add-on of 104%, this almost double the total flame retardant presence with respect to fabric, has minimal effect on LOI. Displayed is the most conservative of the prioritised value(s). Data generally displayed in milligrams per kilogram bodyweight per day. All data remain the property of its respective owners.Note that the brief profile is an automatically generated summary and that not all available data may be displayed. Otherwise data is displayed reported as provided by the registrant(s).The availability of additional data beyond the five results displayed is indicated by (…). It is possible that the harmonisation is introduced through an amendment to the CLP Regulation. In case the substance classification is not harmonised and the substance is not registered the properties are derived from classifications provided in CLP notifications. The dibenzo derivative (8) was prepared from o-xylidene dibromide 〈73JHC395〉. Other release to the environment of this substance is likely to occur from: outdoor use in long-life materials with low release rate (e.g. The following examples are given by way of illustration of the present invention and should not be construed to limit the scope of the invention. Short-term EC50 or LC50 for mammals provides substance information on the substance’s effect concentration or lethal concentration (short term) for 50% of mammals in the test, generally displayed in milligram per kilo food. Values are generally displayed in milligrams per kilogram (dry weight). 615218 ; 98 atom % D; Sigma-Aldrich pricing SDS. Note: Registrants can also select ‘other’ as the test species, dose descriptor type and/or the unit of measure. The basis of SMILES is the representation of a valence model of a molecule. Resorcinol bis(di-2,6-xylenyl phosphate) (RXP) is exclusively made in Japan and has a higher hydrolytic stability than RDP and BDP due to the steric hindrance by the 2,6-xylyl groups. 1000 mg/m 3 See: 115866. Please upgrade your Internet Explorer to a newer version. See information under ‘Applicant’s summary and conclusion – interpretation of results (oral)’. Oxidation reduction potential in mV at 20°C provides substance information on the substance’s oxidation reduction measured in millivolts at a temperature of 20°C. These housings are made of different types of polymer resins such as high-impact polystyrene (HIPS), acrylonitrile butadiene styrene (ABS) copolymers, polycarbonate (PC)/ABS blends (PC/ABS), and polyphenylene ether (PPE)/HIPS blends (PPE/HIPS). Surface tension provides substance information on the surface tension in (milli)Newton per metre in a concentration in (milli)gram per metre and at a temperature measured in °C. Triphenyl phosphate (TPP) is a triester of phosphoric acid and phenol. Data is generally displayed in milligram per kilo bodyweight. : 681357: Relevant identified uses of the substance or mixture: Identified: Laboratory chemical uses: R&D: Uses advised against: HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. Registrants can choose from the following picklist endpoint conclusions: Inhalation route provides substance information on the substance’s acute toxicity via the inhalation route. With a density of 1.2055 g/cm³ at 50 °C triphenyl phosphate is heavier than water (Lide, 1995). Although some specific phosphorus products seem to occasionally find mention in the discussions on environmentally not-so-friendly products, phosphorus-containing FR products have not been banned or restricted in any way to date. EPA has determined that TPP is a suitable candidate for the proposed designation as a high-priority substance. This section summarises the values related to phototransformation in air from all registered dossiers for the substance. Description; Table Of Content; The Global Triphenyl Phosphate(TPP) Industry 2016 Market Research Report is a professional and in-depth study on the current state of the Triphenyl Phosphate(TPP) industry. Short-term EC50 or LC50 for soil microorganisms provides substance information on the substance’s effect concentration or lethal concentration (short term) for 50% of soil microorganisms in the test, generally displayed in milligram per kilo soil (dry weight). phosphate photographic silver silver halide antifoggants Prior art date 1967-04-06 Legal status (The legal status is an assumption and is not a legal conclusion. Processable data for study results is prioritised by test species (see list below) and subsequently further prioritised by the dose descriptor. BOD5 provides substance information on the substance’s BOD5 values displayed in O2 (milli)gram per gram test material. Values are generally displayed in milligram per kilo food. Butylated Triphenyl Phosphate Market value is anticipated to grow at 4.83%, In the report, Butylated Triphenyl Phosphate Market has been studied for North America, Europe, Asia-Pacific, the Middle East & Africa, and Central & South. Another commercially available bisphosphate is RXP. This substance is used in the following activities or processes at workplace: mixing in open batch processes, roller or brushing applications, treatment of articles by dipping and pouring, laboratory work, hand mixing with intimate contact only with personal protective equipment available and the low energy manipulation of substances bound in materials or articles. This substance is used in the following products: adhesives and sealants and cosmetics and personal care products. Triphenyl phosphate Compound Information and Applications for GC (Gas Chromatography) and LC (Liquid Chromatography) Analysis Stars This entity has been manually annotated by the ChEBI Team. These notifications can be provided by manufacturers, importers and downstream users. The phosphorus FR product group includes many phosphorus-containing compounds including organic phosphates, phosphonates, phosphate-and-halogen containing compounds, APP, and red phosphorus. If more than one numerical result is available per endpoint, the range of results (min–max) and range of experimental conditions will be presented (RANGE method). Triphenyl phosphate (TPHP) is an unsubstituted aryl phosphate ester that is widely used as an additive flame ... Santa Clara, California), respectively. Monofunctional phosphates made by reacting cyclic acid phosphates with propylene oxide or ethylene oxide. Background Triphenyl phosphate (TPhP) is an environmental PPARγ ligand, and growing evidence suggests that it is a metabolic disruptor. PBT properties are derived from REACH registered substances dossiers. FIGURE 3. Note: If the measurement condition (percentage of organic carbon) is not provided by the registrant for adsorption coefficient Kd, the data provided is not processed for the Brief Profile. melamine phosphate (Antiblaze NH, Albemarle). This section summarises the values related to short term toxicity to aquatic invertebrates from all registered dossiers for the substance. The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). Triphenyl phosphate is a solid substance at room temperature with a melting point of about 48 - 50 °C and a boiling point of 245 °C (at 14.6 hPa) (Merck Index, 1996). Read product labels carefully and talk to your doctor if you have any questions. This section provides information on the derived no- or minimal effect level (DN(M)EL), the level of exposure above which a human should not be exposed to a substance. A handful of animal studies and in vitro studies have suggested that it could be an endocrine disrupter which affects your hormones – in particular, it could potentially affect reproductive health and lipid metabolism (that’s where the “nail polish makes you fat” headline comes from). Triphenyl phosphate (TPhP) is the chemical compound with the formula OP(OC 6 H 5) 3.This colourless solid is the ester (triester) of phosphoric acid and phenol.It is used as a plasticizer and a fire retardant in a wide variety of settings and products.. The ratio of PC and ABS in the section help of the prioritised value s... Infringements that may be updated to reflect the registered tonnage band ( s triphenyl phosphate is an example for within five. 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